Which one of the following molecules will form a linear polymeric structure due to H-bonding?

Which one of the following molecules will form a linear polymeric structure due to H-bonding?
  1. $\mathrm{HCl}$
  2. HF
  3. $\mathrm{H}_{2} \mathrm{O}$
  4. $\mathrm{NH}_{3}$

Solution

HCl does not form hydrogen bonds. HF forms a linear polymeric structure due to strong hydrogen bonding. $\mathrm{NH}_3$ does not form a polymeric structure due to weak hydrogen bonds. $\mathrm{H}_2 \mathrm{O}$ forms a tetrahedral polymeric structure, not linear. Thus, the correct answer is HF. *

Asked in: JEE-TOPICTESTS-CHEMISTRY

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