Which one of the following molecules contain no $\pi$-bond?

Which one of the following molecules contain no $\pi$-bond?
  1. $\mathrm{CO}_2$
  2. $\mathrm{H}_2 \mathrm{O}$
  3. $\mathrm{SO}_2$
  4. $\mathrm{NO}_2$

Solution

All the molecules have $\mathrm{O}$ atom with lone pairs, but in $\mathrm{H}_2 \mathrm{O}$ the $\mathrm{H}$ atom has no vacant orbital for $\pi$ bonding. That's why it does not have any $\pi$ bond. In all other given molecules, the central atom because of the presence of vacant orbitals is capable to farm $\pi$ bonds.

Asked in: NEET 2013 (All India)

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