Which one of the following molecular hydrides acts as a Lewis acid ?

Which one of the following molecular hydrides acts as a Lewis acid ?
  1. $\mathrm{NH}_3$
  2. $\mathrm{H}_2 \mathrm{O}$
  3. $\mathrm{B}_2 \mathrm{H}_6$
  4. $\mathrm{CH}_4$

Solution

Key Idea:- Electron deficient molecules behave as Lewis acid. Among the given molecules, only diborane is electron deficient, ie, does not have complete octet. Thus, it acts as a Lewis acid. $\mathrm{NH}_3$ and $\mathrm{H}_2 \mathrm{O}$ being electron rich molecules behave as Lewis base.

Asked in: NEET 2010 (Screening)

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