Which one of the following is the strongest base in aqueous solution?

Which one of the following is the strongest base in aqueous solution?
  1. Trimethylamine
  2. Aniline
  3. Dimethylamine
  4. Methylamine

Solution

In aqueous solution basicity order of $1^{\circ}, 2^{\circ}$ and $3^{\circ}$ amine with methyl group is $2^{\circ}>1^{\circ}>3^{\circ}$ In case of aniline lone pair of nitrogen is involved in resonance, so it is weaker base than aliphatic amines. Hence, (C) is correct.

Asked in: JEE Main 2007

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