Which one of the following is formed apart from sodium chloride when chlorine reacts with hot concentrated…

Which one of the following is formed apart from sodium chloride when chlorine reacts with hot concentrated sodium hydroxide?
  1. $\mathrm{NaOCl}$
  2. $\mathrm{NaClO}_3$
  3. $\mathrm{NaClO}_2$
  4. $\mathrm{NaClO}_4$

Solution

When chlorine reacts with hot concentrated sodium hydroxide, sodium chloride, sodium chlorate and water are obtained. $\mathrm{Cl}_2(g)+\underset{\text { (hot conc) }}{6 \mathrm{NaOH}} \stackrel{70^{\circ} \mathrm{C}}{\longrightarrow} 5 \mathrm{NaCl}$ $+\underset{\text { sodium chlorate }}{\mathrm{NaClO}_3}+3 \mathrm{H}_2 \mathrm{O}$

Asked in: AP EAMCET 2010

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