Which one of the following involves decrease in entropy?

Which one of the following involves decrease in entropy?
  1. $2 \mathrm{NaHCO}_{3(s)} \longrightarrow \mathrm{Na}_2 \mathrm{CO}_{3(s)}+\mathrm{CO}_{2(g)}+\mathrm{H}_2 \mathrm{O}_{(g)}$
  2. $\mathrm{CCl}_{4(s)} \longrightarrow \mathrm{CCl}_{4(l)}$
  3. $\mathrm{Zn}_{(s)}+2 \mathrm{HCl}_{(a q)} \longrightarrow \mathrm{ZnCl}_{2(a q)}+\mathrm{H}_{2(g)}$
  4. $\begin{aligned} & \mathrm{CaO}_{(s)}+\mathrm{CO}_{2(g)} \longrightarrow \mathrm{CaCO}_{3(s)} \end{aligned}$

Solution

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Asked in: AP EAMCET 2017 (26 Apr Shift 2)

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