$\text {In a } \mathrm{S}_{\mathrm{N}} 2 \text { substitution reaction of the type }$…

$\text {In a } \mathrm{S}_{\mathrm{N}} 2 \text { substitution reaction of the type }$ $\mathrm{R}-\mathrm{Br}+\mathrm{Cl}^{-} \stackrel{\mathrm{OMF}}{\longrightarrow} \mathrm{R}-\mathrm{Cl}+\mathrm{Br}^{-}$ Which one of the following has the highest relative rate?
  1. $\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{Br}$
  2. $\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{CH}_2 \mathrm{Br}$


Solution

For $\mathrm{S}_{\mathrm{N} 2}$ reaction, there should be low steric hinderance for better reactivity.

Asked in: NEET 2008 (Mains)

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