Which one of the following compounds most readily undrgoes substitution by $\mathrm{S}_{\mathrm{N}} 2$…

Which one of the following compounds most readily undrgoes substitution by $\mathrm{S}_{\mathrm{N}} 2$ mechanism?

Solution

The increasing order of the nucleophilic substitution by $\mathrm{S}_{\mathrm{N}} 2$ mechanism is tert
$-$ alkyl halide $ < $ sec alkyl halide $ < $ primary alkyl halide.
Compound B is primary alkyl halide.
Hence it most readily undergoes substitution by $\mathrm{S}_{\mathrm{N}} 2$ mechanism.
Note: compound $\mathrm{A}$ is also primary alkyl halide but in it, the carbon attached to is more hindered. ,

Asked in: JEE-TOPICTESTS-CHEMISTRY

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