Which one of the following aqueous solutions will exhibit the highest boiling point?

Elevation in boiling point is a colligative property which depends upon the number of solute particles.
Greater the number of solute particles in a solution, higher the extent of elevation in boiling point.
${\text{Na}}_2{\text{SO}}_4⟶2{\text{Na}}^{+}+{\text{SO}}_4^{2- }$. On complete dissociation, $\mathrm{i}=3$   ${\left(\Delta {\text{T}}_{\text{b}}\right)}_{{\text{KNO}}_3}=\text{i }{\text{K}}_{\text{b}}·\text{m}\left(\text{i}=2\right)$ ${\left(\Delta {\text{T}}_{\text{b}}\right)}_{\text{urea}}=\text{i}{\text{K}}_{\text{b}}·\text{m}\left(\text{i }=1\right)$ ${\left(\Delta {\text{T}}_{\text{b}}\right)}_{\text{glucose}}=\text{i}{\text{K}}_{\text{b}}·\text{m}\left(\text{i }=1\right)$ ${\left(\Delta {\text{T}}_{\text{b}}\right)}_{{\text{Na}}_2{\text{SO}}_4}=\text{i }{\text{K}}_{\text{b}}·\text{m}\left(\text{i}=3\right)$ The Van't Hoff factor is the highest for ${\mathrm{Na}}_2{\mathrm{SO}}_4$ and will exhibit the highest boiling point_.