Which of the following will have maximum stabilization due to crystal field?

Which of the following will have maximum stabilization due to crystal field?
  1. TiH2O63+
  2. CoH2O62+
  3. CoCN63-
  4. CuNH342+

Solution

CoH2O62+; t2g6eg0; CFSE =-0.4×6+0.6×1Δo+2P=1.8Δo+2P

CoCN63-; t2g6eg0; CFSE =-0.4×6+0.6×0Δo+2P=2.4Δo+2P

Since CN-1 is a strong field ligand, Δo of this complex will be higher than that of CoH2O63+

Asked in: JEE Main 2022 (27 Jun Shift 1)

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