Which of the following statement is correct for the reactivity in S N 2 reaction?

Which of the following statement is correct for the reactivity in S N 2 reaction?
  1.  is more reactive than 
  2. is more reactive than
  3.  is more reactive than 
  4.  is more reactive than 

Solution

The electronegativity order of hybridized carbons is s p > s p 2 > s p 3 . So in an allylic halide, such as C H 2 = C H - C H 2 - I , the alpha carbon is much more partially positive than the alpha carbon in C H 3 - C H 2 - C H 2 I . Therefore, the attacking nucleophile will be attracted to the alpha carbon more in the allylic halide compound than in the primary halide. Hence, allylic halides tend to follow S N 2 pathways more than primary halides.

Asked in: JEE-TOPICTESTS-CHEMISTRY

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