Which of the following reaction is an example of ammonolysis?

Which of the following reaction is an example of ammonolysis?

$C_{6} H_{5} COCl + C_{6} H_{5} {NH}_{2} ⟶ C_{6} H_{5} {CONHC}_{6} H_{5}$
$C_{6} H_{5} {CH}_{2} CN \overset{[H]}{⟶} C_{6} H_{5} {CH}_{2} {CH}_{2} {NH}_{2}$
$C_{6} H_{5} {NH}_{2} \overset{HCl}{⟶} C_{6} H_{5} {NH}_{3} {Cl}^{-}$
$C_{6} H_{5} {CH}_{2} Cl + {NH}_{3} ⟶ C_{6} H_{5} {CH}_{2} {NH}_{2}$

Solution

The process of cleavage of the $C - X$ bond by Ammonia molecule is known as ammonolysis.

$Ex : R - {CH}_{2} - Cl + \ddot{N} H_{3} ⟶ R - {CH}_{2} - {NH}_{2}$

Asked in: JEE Main 2021 (17 Mar Shift 1)

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