Which of the following pair of compounds demonstrates the law of multiple proportions?

Which of the following pair of compounds demonstrates the law of multiple proportions?
  1. $\mathrm{CH}_4, \mathrm{CCl}_4$
  2. $\mathrm{BF}_3, \mathrm{NH}_3$
  3. $\mathrm{CO}, \mathrm{CO}_2$
  4. $\mathrm{NO}_2, \mathrm{CO}_2$

Solution

$\mathrm{CO}, \mathrm{CO}_2$,as these two compounds consist of the same two elements, carbon and oxygen, which combine in different simple numerical ratios, fulfilling the criteria of the law of multiple proportions.

Asked in: MHT CET 2023 (14 May Shift 2)

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