Which of the following oxoacids of phosphorus is a reducing agent and a monobasic acid as well?

Which of the following oxoacids of phosphorus is a reducing agent and a monobasic acid as well?
  1. $\mathrm{H}_4 \mathrm{P}_2 \mathrm{O}_5$
  2. $\mathrm{HPO}_3$
  3. $\mathrm{H}_3 \mathrm{PO}_3$
  4. $\mathrm{H}_3 \mathrm{PO}_2$

Solution

Acids which contain $\mathrm{P}-\mathrm{H}$ bonds have strong reducing properties. Hypophosphorus acid $\left(\mathrm{H}_3 \mathrm{PO}_2\right)$ is a good reducing agent as it contains two $\mathrm{P}-\mathrm{H}$ bonds. It has one $\mathrm{P}-\mathrm{OH}$ bond, so it is monobasic.

Asked in: NEET 2023 (All India)

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