Which of the following order is wrong?

Which of the following order is wrong?
  1. $\mathrm{NH}_3 < \mathrm{PH}_3 < \mathrm{AsH}_3$ - Acidic
  2. $\mathrm{Li} < \mathrm{Be} < \mathrm{B} < \mathrm{C}-$ First ionization potential
  3. $\mathrm{Al}_2 \mathrm{O}_3 < \mathrm{MgO} < \mathrm{Na}_2 \mathrm{O} < \mathrm{K}_2 \mathrm{O}-$ Basic
  4. $\mathrm{Li}^{+} < \mathrm{Na}^{+} < \mathrm{K}^{+} < \mathrm{Cs}^{+}-$Ionic radius

Solution

$\mathrm{Li}, \mathrm{Be}, \mathrm{B}, \mathrm{C}$ - these elements belong to the same period. Generally, the value of 1 st ionisation potential increases in moving from left to right in a period, since the nuclear charge of the elements also increase in the same direction. But the ionisation potential of boron $\left(\mathrm{B} \rightarrow 2 s^2 p^1\right)$ is lower than that of beryllium (Be $\rightarrow 2 s^2$ ), since in case of boron, $2 p^1$ electron have to be removed to get $\mathrm{B}^{+}$, while in case of $\mathrm{Be}, 2 s^2$ electron have to be removed to get $\mathrm{Be}^{+}\left(2 s^1\right)$. $p$ electron can be removed more easily than $s$ electron so the energy required to remove electron will be less in case of boron. The order will be $\mathrm{Li} < \mathrm{B} < \mathrm{Be} < \mathrm{C}$

Asked in: NEET 2002

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