Which of the following molecule has bond order 2?

Which of the following molecule has bond order 2?
  1. $\mathrm{N}_2$
  2. $\mathrm{H}_2$
  3. $\mathrm{O}_2$
  4. $\mathrm{F}_2$

Solution

The electronic configuration of $\mathrm{O}_2$ molecule is $\begin{aligned} & (\sigma 1 \mathrm{~s})^2\left(\sigma^* 1 \mathrm{~s}\right)^2(\sigma 2 \mathrm{~s})^2\left(\sigma^* 2 \mathrm{~s}\right)^2\left(\sigma 2 \mathrm{p}_{\mathrm{z}}\right)^2\left(\pi 2 \mathrm{p}_{\mathrm{x}}\right)^2 \\ & \left(\pi 2 \mathrm{p}_{\mathrm{y}}\right)^2\left(\pi^* 2 \mathrm{p}_{\mathrm{x}}\right)^1\left(\pi^* 2 \mathrm{p}_{\mathrm{y}}\right)^1 \end{aligned}$
Bond order of $\mathrm{O}_2$ molecule $=\frac{\mathrm{N}_{\mathrm{b}}-\mathrm{N}_{\mathrm{a}}}{2}=\frac{10-6}{2}=2$

Asked in: MHT CET 2024 (10 May Shift 1)

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