Which of the following ionic species has the greatest proton affinity to form stable compound?

Which of the following ionic species has the greatest proton affinity to form stable compound?
  1. $\mathrm{NH}_2^{-}$
  2. $\mathrm{F}^{-}$
  3. $1^{-}$
  4. $\mathrm{HS}^{-}$

Solution

Proton affinity decreases in moving across the period from left to right due to increase in charge. Within a group the proton affinities decreases from top to bottom. $\Rightarrow$ Proton affinity $\rightarrow$ Nitrogen family $ > $ Oxygen family $ > $ Halogens

Asked in: NEET 2007

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