Which of the following formula represents lithium imide?

Which of the following formula represents lithium imide?
  1. $\mathrm{L} \mathrm{i}_{3} \mathrm{~N}$
  2. $\mathrm{LiNH}_{2}$
  3. $\mathrm{Li}_{2} \mathrm{NH}$
  4. LiNH

Solution

$\mathbf{L i}_{2} \mathrm{NH}$ The inorganic compound lithium imide has the chemical formula NH. A reaction between lithium amide and lithium hydride can produce this whitish substance. $\mathrm{LiH}_{2}+\mathrm{LiH} \longrightarrow \mathrm{Li}_{2} \mathrm{NH}+\mathrm{H}_{2}$ Lithium Imlde The product is sensitive to light and can be disproportionated to generate lithium nitride.

Asked in: MHT CET 2020 (16 Oct Shift 2)

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