Which of the following elements in their respective oxidation states does not develop spin only magnetic…

Which of the following elements in their respective oxidation states does not develop spin only magnetic moment? $\text { [Ti }(\mathrm{Z}=22), \mathrm{Zn}(\mathrm{Z}=30), \mathrm{V}(\mathrm{Z}=23), \mathrm{Cu}(\mathrm{Z}=29)]$
  1. $\mathrm{Cu}^{2+}$
  2. $\mathrm{Zn}^{2+}$
  3. $\mathrm{Ti}^{3+}$
  4. $\mathrm{V}^{3+}$

Solution

Spin only magnetic moment $=\sqrt{\mathrm{n}(\mathrm{n}+2)}$ $\mathrm{n}=$ no. of unpaired electrons $\mathrm{Zn}^{2+} \Rightarrow[\mathrm{Ar}] 3 \mathrm{~d}^{10}$ $\mathrm{n}=0$ Spin only magnetic moment $=0$

Asked in: MHT CET 2021 (24 Sep Shift 1)

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