Which of the following conditions are not suitable for a spontaneous reaction?

Which of the following conditions are not suitable for a spontaneous reaction?
  1. $\Delta H < 0$ and $\Delta S>0$ at low temperature.
  2. $\Delta H < 0$ and $\Delta S < 0$ at high temperature.
  3. $\Delta H > 0$ and $\Delta S < 0$ at low temperature.
  4. $\Delta H>0$ and $\Delta S>0$ at high temperature.

Solution

$\Delta G$ (Gibbs' free energy) must be negative for a spontaneous reaction. Using Gibbs' free energy equation, we can find favourable conditions. $\Delta G=\Delta H-T \Delta S\left[\begin{array}{l}\Delta H=\text { Change in enthalpy } \\ \Delta S=\text { Change in entropy } \\ T=\text { Temperature }\end{array}ight]$

Asked in: JEE-TOPICTESTS-CHEMISTRY

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