Which of the following, compounds is the reactant in Rosenmund's reduction?

Which of the following, compounds is the reactant in Rosenmund's reduction?
  1. $\mathrm{CH}_3 \mathrm{CO}_2 \mathrm{H}$
  2. $\mathrm{CH}_3 \mathrm{CHO}$
  3. $\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{Cl}$
  4. $\mathrm{CH}_3 \mathrm{COCl}$

Solution

Rosenmund's reduction involves the reduction of acid halide into aldehyde by means of $\mathrm{Pd} / \mathrm{BaSO}_4$. $\mathrm{CH}_3 \mathrm{COCl} \stackrel{\mathrm{Pd} / \mathrm{BaSO}_4}{\stackrel{\mathrm{H}_2}{\longrightarrow}} \mathrm{CH}_3 \mathrm{CHO}+\mathrm{HCl}$

Asked in: AP EAMCET 2005

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