Which of the following compounds give a ketone with grignard reagent?

Which of the following compounds give a ketone with grignard reagent?
  1. Formaldehyde
  2. Ethyl alcohol
  3. Methyl cyanide
  4. Methyl iodide

Solution

Methyl cyanide gives a ketone with grignard reagent. For example, methylcyanide reacts with methyl magnesium bromide to form an adduct magnesium bromide propan-2-ylideneamide which on hydrolysis gives propan-2-one.
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Asked in: JEE-TOPICTESTS-CHEMISTRY

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