Which of the following compound is added to the sodium extract before addition of silver nitrate for testing…

Which of the following compound is added to the sodium extract before addition of silver nitrate for testing of halogens?
  1. Nitric acid
  2. Sodium hydroxide
  3. Ammonia
  4. Hydrochloric acid

Solution

For testing of halogens, Nitric acid is added to the sodium extract because if CN- or S2- are present then they will be oxidised and removed before the test of halides.

NaCN+HNO3NaNO3+HCN
Na2S+HNO3NaNO3+H2S
Nilnic acid decomposed NaCN & Na2S, else they precipitate in test & misquite the resolve

Asked in: JEE Main 2021 (25 Feb Shift 2)

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