Which of the following $f$-block element exhibits the highest oxidation state?

Which of the following $f$-block element exhibits the highest oxidation state?
  1. $U$
  2. $\mathrm{Np}$
  3. $\mathrm{Am}$
  4. $\mathrm{Pa}$

Solution

\begin{array}{llll} \hline Element & \begin{array}{l} Atomic \\ number \end{array} & Configuration & \begin{array}{l} Oxidation \\ states \end{array} \\ \hline \mathrm{U} & 92 & {[\mathrm{Rn}] 5 f^3 6 d^1 7 s^2} & \begin{array}{l} +3,+4, \\ +5,+6 \end{array} \\ \hline \mathrm{Np} & 93 & {[\mathrm{Rn}] 5 f^4 6 d^1 7 s^2} & \begin{array}{l} +3,+4, \\ +5,+6,+7 \end{array} \\ \hline \mathrm{Am} & 95 & {[\mathrm{Rn}] 5 f^7 7 s^2} & +3,+4, \\ & & & +5,+6 \\ \hline \mathrm{Pa} & 91 & {[\mathrm{Rn}] 5 f^2 6 d^1 7 s^2} & +3,+4,+5 \\ \hline \end{array} Thus, Np exhibits highest oxidation state.

Asked in: AP EAMCET 2022 (06 Jul Shift 2)

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