Which of the following atoms, in its ground state has the highest number of unpaired electrons?

Which of the following atoms, in its ground state has the highest number of unpaired electrons?
  1. Chromium $[Z=24]$
  2. Iron $[Z=26]$
  3. Manganese $[Z=25]$
  4. Vanadium $[Z=23]$

Solution

(a) Chromium ( $Z=24$ ) Electronic configuration $(\mathrm{EC})=[\mathrm{Ar}] 3 d^5 4 s^1$
Number of unpaired electrons in $\mathrm{Cr}=6$ (b) Iron $(Z=26)$ $\mathrm{EC}=[\mathrm{Ar}] 3 d^6 4 s^2$
(c) Manganese $(Z=25)$ $\mathrm{EC}=[\mathrm{Ar}] 3 d^5 4 s^2$
(d) Vanadium $(Z=23)$, $\mathrm{EC}=[\mathrm{Ar}] 3 d^3 4 s^2$
Number of unpaired electrons $=3$ So, chromium $(\mathrm{Cr})$ has maximum unpaired electron.

Asked in: AP EAMCET 2021 (23 Aug Shift 2)

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