Which from following coordinate complexes is a heteroleptic complex?

Which from following coordinate complexes is a heteroleptic complex?
  1. Pentacarbonyliron(0)
  2. Triamminetrinitrocobalt(III)
  3. Tetraamminecopper(II) ion
  4. Tetracyanonickelate(II) ion

Solution

In triamminetrinitrocobalt(III), i.e., $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3\left(\mathrm{NO}_2\right)_3\right]$, two different ligands are attached to the central metal ion. Therefore, it is heteroleptic complex.

Asked in: MHT CET 2024 (09 May Shift 1)

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