Which element of the \(3 d\)-series has highest third ionisation enthalpy?

Which element of the \(3 d\)-series has highest third ionisation enthalpy?
  1. \(\mathrm{Mn}\)
  2. \(\mathrm{Zn}\)
  3. \(\mathrm{Fe}\)
  4. \(\mathrm{Cu}\)

Solution

The electronic configuration of zinc metal is \(\mathrm{Zn} \Rightarrow[\mathrm{Ar}] 3 d^{10}, 4 s^2\) The third ionisation enthalpy of \(\mathrm{Zn}\) means removal of electron from the stable configuration of \(3 d^{10}\). The metal having the highest third ionisation enthalpy is \(\mathrm{Zn}\). Hence, the correct option is (b). *

Asked in: JEE-TOPICTESTS-CHEMISTRY

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