Which among the following statements about $\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}$ is NOT true?

Which among the following statements about $\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}$ is NOT true?
  1. In this electron are paired prior to hybridization
  2. Oxidation state of $\mathrm{Ni}$ is +6
  3. Ni undergoes dsp ${ }^2$ hybridization
  4. It is a square planar complex

Solution

$\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-} \Rightarrow \mathrm{Ni}^{2+}$ Oxidation state of $\mathrm{Ni}$ is +2 - $\quad \mathrm{CN}^{-}$is strong field ligand. - $\quad$ Electrons are paired prior to hybridization. $\mathrm{Ni}^{2+}[\mathrm{Ar}] 3 \mathrm{~d}^8$ - $\quad \mathrm{dsp}^2$ hybridization and square planar complex.

Asked in: MHT CET 2021 (22 Sep Shift 2)

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