Which among the following salt solution in water is acidic in nature?

Which among the following salt solution in water is acidic in nature?
  1. $\mathrm{CuCl}_2$
  2. $\mathrm{NH}_4 \mathrm{CN}$
  3. $\mathrm{KCN}$
  4. $\mathrm{CH}_3 \mathrm{COONa}$

Solution

(1) $\mathrm{CuCl}_2$ : Salt of strong acid and weak base: Solution is acidic. (2) $\mathrm{NH}_4 \mathrm{CN}$ : Salt of weak acid and weak base for which $\mathrm{K}_{\mathrm{a}} < \mathrm{K}_{\mathrm{b}}$ : Solution is basic. (3) $\mathrm{KCN}$ : Salt of weak acid and strong base: Solution is basic. (4) $\mathrm{CH}_3 \mathrm{COONa}$ : Salt of weak acid and strong base: Solution is basic.

Asked in: MHT CET 2023 (13 May Shift 2)

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