Which among the following reactions does NOT form alkyl halides?

Which among the following reactions does NOT form alkyl halides?
  1. Alcohol reacts with halogen in presence of sunlight.
  2. Alcohol reacts with $\mathrm{HCl}$ in presence of anhydrous $\mathrm{ZnCl}_2$.
  3. Alcohol reacts with $\mathrm{HBr}$ in presence of $\mathrm{NaBr}, \mathrm{H}_2 \mathrm{SO}_4$.
  4. Alcohol reacts with $\mathrm{HI}$ in presence of $\mathrm{NaI} / \mathrm{H}_3 \mathrm{PO}_4$.

Solution

Alcohol reacts with halogen in presence of sunlight does not form alkyl halides.

Asked in: MHT CET 2022 (05 Aug Shift 1)

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