When $1 \mathrm{~kg}$ of ice at $0^{\circ} \mathrm{C}$ melts to water at $0^{\circ} \mathrm{C}$, the…

When $1 \mathrm{~kg}$ of ice at $0^{\circ} \mathrm{C}$ melts to water at $0^{\circ} \mathrm{C}$, the resulting change in its entropy, taking latent heat of ice to be $80 \mathrm{cal} /{ }^{\circ} \mathrm{C}$, is
  1. $273 \mathrm{cal} / \mathrm{K}$
  2. $253 \mathrm{cal} / \mathrm{K}$
  3. $263 \mathrm{cal} / \mathrm{K}$
  4. $293 \mathrm{cal} / \mathrm{K}$

Solution

Change in entropy is given by $\mathrm{dS}=\frac{\mathrm{dQ}}{\mathrm{T}}$ or $\Delta \mathrm{S}=\frac{\Delta \mathrm{Q}}{\mathrm{T}}=\frac{\mathrm{mL}_{\mathrm{f}}}{273}$
$\Delta \mathrm{S}=\frac{1000 \times 80}{273}=293 \mathrm{cal} / \mathrm{K}$ *

Asked in: JEE-TOPICTESTS-CHEMISTRY

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