When a hydrocarbon A undergoes combustion in the presence of air, it requires 9 . 5 equivalents of oxygen…

When a hydrocarbon A undergoes combustion in the presence of air, it requires 9.5 equivalents of oxygen and produces 3 equivalents of water. What is the molecular formula of A?
  1. C8H6
  2. C9H9
  3. C6H6
  4. C9H6

Solution

CxHy+x+y4O2xCO2+y2H2O

Number of equivalents of O2 = Number of equivalents of H2O

Number of equivalents of H2O = y2=3  y = 6

Number of equivalents of O2 = x+y4= 9.5

x + 64 = 9.5

 x + 1.5 = 9.5

 x = 9.5 - 1.5 = 8

x=8, y=6.

So, the formula is C8H6.

Asked in: JEE Main 2023 (29 Jan Shift 2)

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