What type of alcohol is the crotonyl alcohol?

What type of alcohol is the crotonyl alcohol?
  1. Allylic alcohol
  2. Benzylic alcohol
  3. Vinylic alcohol
  4. Polyhydric alcohol

Solution

Crotonyl alcohol has the structure $\mathrm{CH}_3-\mathrm{CH}=\mathrm{CH}-\mathrm{CH}_2-\mathrm{OH}$, where the hydroxyl group is bonded to a saturated carbon atom adjacent to a carbon-carbon double bond. This defines it as an allylic alcohol.

Among the options, allylic alcohol describes an alcohol with the $-\mathrm{OH}$ group on an $\mathrm{sp}^{3}$ carbon adjacent to a double bond, benzylic alcohol requires an aromatic ring, vinylic alcohol has the $\mathrm{-OH}$ directly attached to an $\mathrm{sp}^{2}$ carbon of the double bond, and polyhydric alcohol contains multiple hydroxyl groups. Only allylic alcohol matches the structure.

The classification is therefore $\boxed{A}$.

Asked in: MHT CET 2025 (05 May Shift 2)

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