What time is required for 100 g of reactant to reduce to 25 g in a first order reaction having half life…
What time is required for 100 g of reactant to reduce to 25 g in a first order reaction having half life 5760 year?
- 4760 year
- 8640.26 year
- 2880.15 year
- 11526.48 year
Solution
For a first order reaction,
$\begin{aligned}
& {\left[\mathrm{A}_0\right]=100 \mathrm{~g} ;\left[\mathrm{A}_{\mathrm{t}}\right]=25 \mathrm{~g} ; \mathrm{t}_{1 / 2}=5760 \text { years } } \\
& \mathrm{k}=\frac{0.693}{\mathrm{t}_{1 / 2}}=\frac{0.693}{5760 \mathrm{yr}}=1.203 \times 10^{-4} \text { year }^{-1} \\
& \mathrm{t}=\frac{2.303}{\mathrm{k}} \log _{10} \frac{\left[\mathrm{~A}_0\right]}{\left[\mathrm{A}_{\mathrm{t}}\right]} \\
\therefore \quad & \mathrm{t}=\frac{2.303}{1.203 \times 10^{-4} \text { year }^{-1}} \log _{10} \frac{100}{25} \\
& =19141.8 \times 0.6021=11526.5 \text { years }
\end{aligned}$
Asked in: MHT CET 2024 (03 May Shift 1)
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