What time is required for 100 g of reactant to reduce to 25 g in a first order reaction having half life…

What time is required for 100 g of reactant to reduce to 25 g in a first order reaction having half life 5760 year?
  1. 4760 year
  2. 8640.26 year
  3. 2880.15 year
  4. 11526.48 year

Solution

For a first order reaction, $\begin{aligned} & {\left[\mathrm{A}_0\right]=100 \mathrm{~g} ;\left[\mathrm{A}_{\mathrm{t}}\right]=25 \mathrm{~g} ; \mathrm{t}_{1 / 2}=5760 \text { years } } \\ & \mathrm{k}=\frac{0.693}{\mathrm{t}_{1 / 2}}=\frac{0.693}{5760 \mathrm{yr}}=1.203 \times 10^{-4} \text { year }^{-1} \\ & \mathrm{t}=\frac{2.303}{\mathrm{k}} \log _{10} \frac{\left[\mathrm{~A}_0\right]}{\left[\mathrm{A}_{\mathrm{t}}\right]} \\ \therefore \quad & \mathrm{t}=\frac{2.303}{1.203 \times 10^{-4} \text { year }^{-1}} \log _{10} \frac{100}{25} \\ & =19141.8 \times 0.6021=11526.5 \text { years } \end{aligned}$

Asked in: MHT CET 2024 (03 May Shift 1)

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