What is \(X\) in the following reaction? \(\mathrm{CO}+2 \mathrm{H}_2 \xrightarrow{X} \mathrm{CH}_3…

What is \(X\) in the following reaction? \(\mathrm{CO}+2 \mathrm{H}_2 \xrightarrow{X} \mathrm{CH}_3 \mathrm{OH}\)
  1. \(623 \mathrm{~K} / 300 \mathrm{~atm}\)
  2. \(\mathrm{KMnO}_4 / \mathrm{H}^{\oplus}\)
  3. \(\mathrm{Zn} / \Delta\)
  4. \(\mathrm{ZnO}-\mathrm{Cr}_2 \mathrm{O}_3, 200-300 \mathrm{~atm}, 573-673 \mathrm{~K}\)

Solution

The given reaction is for the industrial preparation methanol from a mixture of carbon monoxide and hydrogen. In the reaction the gaseous mixture is subjected to 200 atmosphere and then passed over heated catalyst mixture of \(\mathrm{ZnO}\) and \(\mathrm{Cr}_2 \mathrm{O}_3\) kept at \(573-673 \mathrm{~K}\). This reaction results the formation of methanol vapours which are then condensed to liquid state. \(\mathrm{CO}+2 \mathrm{H}_2 \xrightarrow[\substack{200-300 \mathrm{~atm}, 573-673 \mathrm{~K}}]{\mathrm{ZnO}-\mathrm{Cr}_2 \mathrm{O}_3(X)} \mathrm{CH}_3 \mathrm{OH}\)

Asked in: AP EAMCET 2019 (22 Apr Shift 1)

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