What is the value of $\mathrm{C}-\mathrm{O}-\mathrm{H}$ bond angle in $\mathrm{CH}_{3}-\mathrm{OH}$ ?

What is the value of $\mathrm{C}-\mathrm{O}-\mathrm{H}$ bond angle in $\mathrm{CH}_{3}-\mathrm{OH}$ ?
  1. $108.9^{\circ}$
  2. $107^{\circ}$
  3. $109.5^{\circ}$
  4. $110^{\circ}$

Solution

$108.9^{\circ}$ Due to repulsion between lone pair electrons of oxygen atoms, the $\mathrm{C}-\mathrm{O}-\mathrm{H}$ bond angle in $\mathrm{CH}_{3}-\mathrm{OH}$ (methanol) is $108.9^{\circ}$. It can be readily demonstrated as follows:

Asked in: MHT CET 2020 (16 Oct Shift 1)

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