What is the coordination number of central metal ion in $\left[\mathrm{Fe}\left(\mathrm{C}_2…

What is the coordination number of central metal ion in $\left[\mathrm{Fe}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}$ ?
  1. 2
  2. 4
  3. 6
  4. 12

Solution

Oxalate ligand (bidentate) $\mathrm{C}_2 \mathrm{O}_4{ }^{2-}$ utilizes electron pair on each of its negatively charged oxygen atoms for linking with central metal. Hence, at a time, it coordinates with the metal ion through 2 oxygen atoms.
Therefore, on binding with 3 oxalate ions, the coordination number of $\mathrm{Fe}^{3+}$ will be 6 .

Asked in: MHT CET 2024 (03 May Shift 1)

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