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What is boiling point of a decimolal aqueous solution of glucose if molal elevation constant for water is $0…
What is boiling point of a decimolal aqueous solution of glucose if molal elevation constant for water is $0.52^{\circ} \mathrm{C} \mathrm{kg} \mathrm{mol}^{-1}$ ?
$101.52^{\circ} \mathrm{C}$ $99.95^{\circ} \mathrm{C}$ $99.48^{\circ} \mathrm{C}$ $100.052^{\circ} \mathrm{C}$
Solution
$\begin{aligned}
& \Delta \mathrm{T}_{\mathrm{b}}=\mathrm{k}_{\mathrm{b}} \cdot \mathrm{m} \\
& \Delta \mathrm{T}_{\mathrm{b}}=0.52 \times 0.1, \mathrm{~m}=0.1 \text { (decimolal solution) } \\
& =0.052^{\circ} \mathrm{C} \\
& \Delta \mathrm{T}_{\mathrm{b}}=\mathrm{T}_{\mathrm{b}}-\mathrm{T}_{\mathrm{b}}^{\circ} \quad\left(\mathrm{T}_{\mathrm{b}}^{\circ}=\right.\text { Boiling point of pure water) } \\
& 0.052^{\circ} \mathrm{C}=\mathrm{T}_{\mathrm{b}}-100^{\circ} \mathrm{C} \\
& \mathrm{T}_{\mathrm{b}}=100.052^{\circ} \mathrm{C}
\end{aligned}$
Asked in: MHT CET 2021 (21 Sep Shift 1)
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