(i) Since $\mathrm{H}_2 \mathrm{O}$ is highly polar in nature and aniline is highly reactive towards electrophilic substitution.
Thus, $\mathrm{Br}_2$ in $\mathrm{H}_2 \mathrm{O}$ gives: 2, 4, 6 tribromo aniline as main product i.e.
and as a result only mono-substituted bromine at $p$-position is the major product i.e.,