Water of mass $m$ gram is slowly heated to increase the temperature from $T_1$ to $T_2$ The change in…

Water of mass $m$ gram is slowly heated to increase the temperature from $T_1$ to $T_2$ The change in entropy of the water, given specific heat of water is $1 \mathrm{Jkg}^{-1} \mathrm{~K}^{-1}$, is :
  1. $\mathrm{m} \ln \left(\frac{\mathrm{T}_2}{\mathrm{~T}_1}\right)$
  2. zero
  3. $\mathrm{m} \ln \left(\frac{\mathrm{T}_1}{\mathrm{~T}_2}\right)$
  4. $\mathrm{m}\left(\mathrm{T}_2-\mathrm{T}_1\right)$

Solution

To determine the change in entropy when water is heated from temperature \(T_1\) to \(T_2\) (here, \(T_\gamma\) is equivalent to \(T_2\) ), we use the definition of entropy change for a reversible process:
\(\Delta S=\int_{T_1}^{T_2} \frac{d Q}{T}\)
Since the water is being heated slowly, the process is reversible, and the heat added is given by:
\(d Q=m c d T\)
where:
- \(m\) is the mass of the water,
- \(c\) is the specific heat capacity (given as \(1 \mathrm{~J} \mathrm{~kg}^{-1} \mathrm{~K}^{-1}\)).
Substitute \(d Q\) into the integral:
\(\Delta S=\int_{T_1}^{T_2} \frac{m c d T}{T}=m c \int_{T_1}^{T_2} \frac{d T}{T}\)
Since \(c=1\), the equation simplifies to:
\(\Delta S=m \int_{T_1}^{T_2} \frac{d T}{T}\)
Evaluating the integral, we have:
\(\int_{T_1}^{T_2} \frac{d T}{T}=\left.\ln T\right|_{T_1} ^{T_2}=\ln \left(\frac{T_2}{T_1}\right)\)
Thus, the change in entropy is:
\(\Delta S=m \ln \left(\frac{T_2}{T_1}\right)\)
Comparing with the options provided, the correct answer is:
Option 1: \(m \ln \left(\frac{T_2}{T_1}\right)\).

Asked in: JEE Main 2025 (23 Jan Shift 2)

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