$\mathrm{AgNO}_3(a q)$ was added to an aqueous $\mathrm{KCl}$ solution gradually and the conductivity of the…
$\mathrm{AgNO}_3(a q)$ was added to an aqueous $\mathrm{KCl}$ solution gradually and the conductivity of the solution was measured. The plot of conductance $(\Lambda)$ versus the volume of $\mathrm{AgNO}_3$ is
$P$
$Q$
$R$
$S$
Solution
As $\mathrm{AgNO}_3$ is added to solution, $\mathrm{KCl}$ will be displaced accrding to following reaction
$
\mathrm{AgNO}_3(a q)+\mathrm{KCl}(a q) \longrightarrow \operatorname{AgCl}(s)+\mathrm{KNO}_3(a q)
$
For every mole of $\mathrm{KCl}$ displaced from solution, one mole of $\mathrm{KNO}_3$ comes in solution resulting in almost constant conductivity. As the end point is reached, added $\mathrm{AgNO}_3$ remain in solution increasing ionic concentration, hence conductivity increases
