Two statements are given below. Statement I: $\mathrm{SnF}_4, \mathrm{PbF}_4$ are ionic in nature Statement…

Two statements are given below. Statement I: $\mathrm{SnF}_4, \mathrm{PbF}_4$ are ionic in nature Statement II: $\mathrm{GeCl}_2$ is more stable than $\mathrm{GeCl}_4$ The correct answer is
  1. Both statements I \& II are correct
  2. Both statements I \& II are not correct
  3. Statement I is correct, but statement II is not correct
  4. Statement I is not correct, but statement II is correct

Solution

In group 14 , most of the $\mathrm{MX}_4$ are covalent in nature exceptions $\mathrm{SnF}_4$ and $\mathrm{PbF}_4$ because there is more electronegativity difference make the bond ionic. So statement I is correct. Ge electronic configuration : $[\mathrm{Ar}] 3 \mathrm{~d}^{10} 4 \mathrm{~s}^2 4 \mathrm{p}^2$ and $\mathrm{Ge}^{+4}$ oxidation is more stable because its allows germanium to achieve a full valence shell, which is energetically more favorable than having an incomplete valence shell in the $\mathrm{Ge}^{+2}$ oxidation state. 'So' only statement I is correct.

Asked in: AP EAMCET 2024 (22 May Shift 2)

Practice more p Block Elements (Group 13 & 14) questions on Aicharya