Total number of unpaired electrons in the complex ions…

Total number of unpaired electrons in the complex ions \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}\) and \(\left[\mathrm{NiCl}_4\right]^{2-}\) is \(\qquad\)

Solution

$\begin{aligned} & \mathrm{Co}^{+3}: 3 \mathrm{~d}^6 \quad \mathrm{t}_{2 \mathrm{~g}}^{2,2,2} \mathrm{e}_{\mathrm{g}}^{0,0} \\ & \text { Unpaired e } \mathrm{e}^{-}=0 \\ & \mathrm{Ni}^{+2}: 3 \mathrm{~d}^8 \quad \mathrm{e}^{2,2} \mathrm{t}_2^{2,1,1} \\ & \text { Unpaired } \mathrm{e}^{-}=2\end{aligned}$

Asked in: JEE Main 2024 (08 Apr Shift 2)

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