Thermal decomposition of $\mathrm{HCOOH}$ is a first order reaction and the rate constant at $T(K)$ is $4…

Thermal decomposition of $\mathrm{HCOOH}$ is a first order reaction and the rate constant at $T(K)$ is $4.606 \times 10^{-3} \mathrm{~s}^{-1}$. The time required to decompose $90 \%$ of initial quantity of $\mathrm{HCOOH}$ at $T(\mathrm{~K})$ in second is
  1. 100
  2. 500
  3. 1000
  4. 50

Solution

First order reaction $ \begin{aligned} & \qquad K=\frac{2.303}{t} \log \frac{A_0}{A} \\ & \text { Given, } K=4.606 \times 10^{-3} \mathrm{~s}^{-1} \\ & A=90 \%, A_0=\text { Initial quantity }=100 \% \\ & t=\frac{2.303}{4.606 \times 10^{-3}} \log \frac{1}{1-9} \\ & t=500 \mathrm{~s} \end{aligned} $

Asked in: AP EAMCET 2018 (22 Apr Shift 1)

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