The work functions of cesium (Cs) and lithium (Li) metals are 1.9 eV and 2.5 eV , respectively. If we…
- Both Cs and Li
- Neither Cs nor Li
- Cs only
- Li only
Solution
The energy of a photon is given by the equation:
\(E=\frac{h c}{\lambda}\)where:
$E=\frac{h c}{\lambda}$ where: $\begin{aligned} & h=6.626 \times 10^{-34} \mathrm{~J} \cdot \mathrm{~s} \text { (Planck's constant), } \\ & c=3.0 \times 10^{8} \mathrm{~m} / \mathrm{s} \text { (speed of light), } \\ & \lambda=550 \mathrm{~nm}=550 \times 10^{-9} \mathrm{~m} \end{aligned}$ First, calculate the photon energy in joules:
\(\begin{gathered}
E=\frac{\left(6.626 \times 10^{-34}\right)\left(3.0 \times 10^8\right)}{550 \times 10^{-9}} \\
E=\frac{1.9878 \times 10^{-25}}{550 \times 10^{-9}} \\
E=3.615 \times 10^{-19} \mathrm{~J}
\end{gathered}\)
Convert this to electron volts (eV) using \(1 \mathrm{eV}=1.6 \times 10^{-19} \mathrm{~J}\) :
\(\begin{gathered}
E=\frac{3.615 \times 10^{-19}}{1.6 \times 10^{-19}} \\
E \approx 2.26 \mathrm{eV}
\end{gathered}\)
Step 2: Compare Photon Energy with Work Functions
Cesium (\(\phi_{\mathrm{Cs}}=1.9 \mathrm{eV}\))
Since \(E_{\text {photon }}=2.26 \mathrm{eV}\) is greater than \(\phi_{\mathrm{Cs}}=1.9 \mathrm{eV}\),photoelectric emission occurs.
Lithium (\(\phi_{\mathrm{Li}}=2.5 \mathrm{eV}\))
Since \(E_{\text {photon }}=2.26 \mathrm{eV}\) is less than \(\phi_{\mathrm{Li}}=2.5 \mathrm{eV}\), photoelectric emission does not occur.
Conclusion:
Photoelectric effect is possible only for Cesium (Cs), but not for Lithium (Li).
Asked in: JEE Main 2025 (22 Jan Shift 1)
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