The types of hybrid orbitals of nitrogen in \(\mathrm{NO}_2^{+}, \mathrm{NO}_3^{-}\)and…

The types of hybrid orbitals of nitrogen in \(\mathrm{NO}_2^{+}, \mathrm{NO}_3^{-}\)and \(\mathrm{NH}_4^{+}\)respectively are
  1. \(s p, s p^3, s p^2\)
  2. \(s p, s p^2, s p^3\)
  3. \(s p^2, s p, s p^3\)
  4. \(s p^2, s p^3, s p\)

Solution

\(\begin{aligned} & \mathrm{NO}_2^{+} \Rightarrow \mathrm{O}=\underset{s p}{\mathrm{~N}} \longrightarrow \mathrm{O} \\ H & =\frac{1}{2}(V+M-C+A) \\ H & =\frac{1}{2}(5+0-1+0)=2(s p) \\ H & =\text { number of hybrid orbitals } \\ V & =\text { number of valence electrons } \\ M & =\text { number of monovalent atoms/groups } \\ C & =\text { number of cationic or positive charge } \\ A & =\text { number of anionic or negative charge } \end{aligned}\)

Asked in: AP EAMCET 2020 (17 Sep Shift 2)

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