The standard emf   for the given cell reaction, Z n + C u 2 + → C u + Z n 2 + is 1 . 10   V…

The standard emf for the given cell reaction, Zn+Cu2+Cu+Zn2+ is 1.10 V at 25. The emf for the cell reaction, when 0.1 M Cu2+ and 0.1 M Zn2+ solutions are used, at 25, is

(Use 2.303RTF=0.059)

  1. -1.10 V
  2. 2.20 V
  3. -2.20 V
  4. 1.10 V

Solution

For the reaction:

Zn+Cu2+Cu+Zn2+

Ecell=Ecell°-0.059nlogZn2+Cu2+

=1.10-0.0592log0.10.1

=1.10 V

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Asked in: JEE-TOPICTESTS-CHEMISTRY

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