The standard electrode potential of M + / M in aqueous solution does not depend on

The standard electrode potential of M+/M in aqueous solution does not depend on

  1. Hydration of a gaseous metal ion
  2. Sublimation of a solid metal

  3. Ionisation of a solid metal atom
  4. Ionisation of a gaseous metal atom

Solution

The stability of M+ ions in aqueous medium depends on three factors: (i) Enthalpy of atomisation (ii) First ionisation enthalpies of isolated gaseous atom (iii) Hydration enthalpy. 

An element in M+ state in aqueous medium is stabler if the electrode potential ( M+/M ) value of more negative. Down the group, the tendency to form M+ ion increases. In this process, ionisation of solid metal is not involved in this process.

Asked in: JEE Main 2023 (06 Apr Shift 1)

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