The second ionisation energies of \(\mathrm{Li}, \mathrm{Be}, \mathrm{B}\) and \(\mathrm{C}\) are in the order

The second ionisation energies of \(\mathrm{Li}, \mathrm{Be}, \mathrm{B}\) and \(\mathrm{C}\) are in the order
  1. L \(>\) C \(>\) B \(>\) Be
  2. Li \(>\) B \(>\) C \(>\) Be
  3. \(\mathrm{Be}>\mathrm{C}>\mathrm{B}>\mathrm{Li}\)
  4. B \(>\) C \(>\) Be \(>\) Li

Solution

The second ionisation energy is the energy required to remove an electron from a \(\mathrm{I}+\) cation in the gaseous state. \(X^{+}(g) \rightarrow X^{2+}(g)+e^{-}\) Just like the first ionisation energy, the second ionisation energy is affected by size, effective nuclear charge, and electron configuration. Li has highest \(\mathrm{IE}_2\) than because the second electron remove from stable noble gas configuration and \(B\) has higer \(\mathrm{IE}_2\) than \(\mathrm{C}\) due to the extra stability of the \(2 s^2\) subshell in the \(\mathrm{B}^{+}\)ion. Therefore, the order is \(\mathrm{Li} > \mathrm{B} > \mathrm{C} > \mathrm{Be}\) Hence, the correct option is (b).

Asked in: AP EAMCET 2020 (21 Sep Shift 1)

Practice more Classification of Elements and Periodicity in Properties questions on Aicharya