The rms velocity of oxygen molecules of $27^{\circ} \mathrm{C}$ is around $800 \mathrm{~m} / \mathrm{s}$.…

The rms velocity of oxygen molecules of $27^{\circ} \mathrm{C}$ is around $800 \mathrm{~m} / \mathrm{s}$. The rms velocity of methane molecule at $600 \mathrm{~K}$ temperature is around ......
  1. $400 \mathrm{~m} / \mathrm{s}$
  2. $1600 \mathrm{~m} / \mathrm{s}$
  3. $800 \mathrm{~m} / \mathrm{s}$
  4. $1200 \mathrm{~m} / \mathrm{s}$

Solution

$v_{\mathrm{rms}}=\sqrt{\frac{3 R T}{M}}$ Let the rms velocity of methane molecule at $600 \mathrm{~K}$ be $x$. $ \begin{aligned} \frac{v_{\mathrm{mss}}\left(\mathrm{O}_2\right)}{v_{\mathrm{ms}}\left(\mathrm{CH}_4\right)} & =\frac{800}{\mathrm{x}}=\frac{\frac{\sqrt{3 R(300 \mathrm{~K})}}{32}}{\frac{\sqrt{3 R(600 \mathrm{~K})}}{16}} \\ & =\frac{800}{x}=\sqrt{\frac{300}{32} \times \frac{16}{600}} \\ \Rightarrow \quad \frac{800}{x} & =\frac{1}{2} \\ x & =1600 \mathrm{~m} / \mathrm{s} \end{aligned} $ Hence, the correct option is (2)

Asked in: AP EAMCET 2020 (22 Sep Shift 1)

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